I found an entire tackle box full of 22LR when I was a kid. They were under water and had been for a long time. Of course I had to try and shoot them.
About 50% went “click”. The other 50% about half were audibly weak. Most had to be wiped off to chamber with effort. I’m amazed I didn’t get one stuck in the bore. I still have that rifle.
I have fired more than a few 19th century rounds. Many more early 20th century. Helping a friend use up all of grandpas old ammo. I would like to have those now.
As a general rule, I found if they turned green, they probably won’t fire. Otherwise, they will probably go off. Antique ammo is much better to collect than shoot.